The Computational Singular Perturbation (CSP) method of simplified kinetics modeling is presented with emphasis on its comparative merits versus conventional methodologies.A new "refinement" procedure for the basis vectors spanning the fast reaction subspace is presented. A simple example is first worked through using the conventional partial-equilibrium and quasi-steady approximations, and is then treated in some detail using CSP.
A liquid film flowing down an inclined heated plane subject to surface wave and thermocapillary instabilities is studied. Three mechanisms exist by which energy can be transferred to the disturbance. Two of these mechanisms are associated with the thermocapillary forces and one with the shear stress of the basic flow at the deformed free surface. Depending on which mechanism is dominant, the instability can assume the form of either long transverse waves or short longitudinal rolls.
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