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The effect of anatase and rutile forms of titanium oxide on the thermal, physicomechanical properties, water absorption and hardness of polycaproamide was studied. It was shown that titanium dioxide has an influence on the degree of crystallinity and the crystallite size. TGA method shows that samples containing rutile and anatase lose weight at a higher temperature than polycaproamide sample without additives. Analysis of the physicomechanical properties of the synthesized samples showed that titanium dioxide in a concentration of 10-4 M increases the strength properties of polycaproamide. At the same time increasing the concentration of titanium dioxide to 10-1 M leads to a decrease in physical and mechanical properties. Anatase and rutile do not have a significant effect on water absorption and polymer hardness.