Sapphires from alluvial deposits associated with Cenozoic basalts in Southern Vietnam were collected for investigation of mineral inclusions. In this report, primary iron oxide inclusions were focused on, with detailed mineral chemistry using a Raman spectroscope and electron probe micro-analyzer. Consequently, a variety of iron oxide inclusions were recognized as wüstite, hercynite, and ilmenite. Ilmenite falling within an ilmenite–hematite series ranged in composition between Il24-30He36-38Mt35-40 and Il49-54He34-40Mt7-10, classified as titanomagnetite and titanohematite, respectively. Wüstite with non-stoichiometry, (Fe2+0.3-0.9)(Ti3+<0.179Al3+≤0.6Cr3+<0.1Fe3+≤0.46)☐≤0.23O, was associated with hercynite inclusions, clearly indicating cogenetic sapphire formation. Wüstite and sapphire appear to have been formed from the breakdown reaction of hercynite (hercynite = sapphire+wüstite) within a reduction magma chamber. Titanohematite and titanomagnetite series might have crystallized during iron–titanium reequilibration via subsolidus exsolution under a slightly oxidized cooling process.
Sedimentary evidence of storms and fluvial floods (FFs) is crucial for a better understanding of such events in coastal zones. In this study, we analyzed the sedimentary characteristics of the coastal storm and FF deposits at the Hoa Duan barrier, Thua Thien Hue, central Vietnam. Analyses of the sedimentary structures and properties (grain size distribution, composition, roundness, and sphericity) and loss on ignition revealed that the storm sediments were comprised of coarser grains with a low organic and carbonated content, and with sedimentary structures, including parallel and inclined landward lamination, multiple sets of normal and reverse grading, mud rip-up clasts, and sharp and erosional contacts (both top and bottom) with finer-grain layers. Conversely, the FF sediments had only fine to very fine grains, with dominant high organic and carbonate contents, and only exhibited sedimentary structures of sharp erosional top and bottom contacts with coarser-grained layers. The clearest differentiation to distinguish coastal storm layers from inland FF layers was obtained by plotting the mean grain size against the sorting. The results of optically stimulated luminescence dating suggested that two storm layers and one FF layer were deposited during the last 130 ± 10 years. Moreover, two layers were deposited by storms and one by a FF prior to that (>130 ± 10 years). The identification of the sedimentary diagnostic key of these two hazards can help to improve the understanding of the geomorphological evolution of the studied site and the other parts of this coastal region in order to remind the coastal community to prepare for future coastal hazards well.
0 50 km 0 400 km their chemical analyses using EPMA. These analytical data lead to a reconstruction of a genetic model of sapphire formation related to basaltic volcanism in this region. They also yield significant information for origin determination by gem testing laboratories.
GEOLOGICAL SETTINGSouthern Vietnam geologically belongs to a largescale structure of the Da Lat active continental margin (Da Lat zone) and the Indosinian polyepisodic orogenic belt (Srepok orogenic belt) (figure 2, left) (Tri and Khuc, 2011), which separated from Gondwana in the Devonian (
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