No abstract

A new 3,3 0 -dibenzoyl-1,1 0 -propan-1,3-diyl)bisthiourea was synthesized by using benzoylisothiocyanate with 1,3-diaminopropane in aprotic solvent. The structure was determinated by means of FT-IR, 1 H-NMR, 13 C-NMR and mass spectroscopic techniques. The crystal structure of 3,3 0 -dibenzoyl-1,1 0 -(propan-1,3-diyl)bisthiourea has also been examined by using X-ray crystallographic techniques and found to be crystallized in the monoclinic space group P2 1 /c with the unit cell parameters: a = 5.968(1) Å , b = 19.471(2) Å , c = 16.585(2) Å , b = 98.32(1)°, V = 1907.0 (4) Å 3 , Dx = 1.395 g cm -3 , and Z = 4 respectively.

The title compound, bis[4 (3' benzoyl)thiocarbamidophenyl]ether, was synthesized by the reac tion of benzoylisothiocyanate with 4,4' diaminodiphenylether in aprotic solvent. The structure was determi nated by means of elemental analysis and FT-IR, 1 H-NMR, 1 3C-NMR and MS spectroscopic techniques. The crystal structure was characterized by X ray syngle crystal analysis: orthorhombic, sp. gr. Pnna, Z = 4. In crystal packing, there are intramolecular hydrogen bond N-H⋅⋅⋅O generating S(6) motif, and intermolecular hydrogen bond N-H⋅⋅⋅S forming (8) ring.