Solar energetic particles (SEPs) are released into the heliosphere by solar flares and coronal mass ejections (CMEs). They are mostly protons, with smaller amounts of heavy ions from helium to iron, and lesser amounts of heavier species than iron. The spectra of heavy ions has been previously studied mostly by using the fluence of the particles in an event integrated spectrum in a small number of spectral snapshots. In this article, we analyze the temporal evolution of the heavy ion spectra using two large SEP events (27 January 2012 and 7 January 2014) from the Solar TErrestrial Relations Observatory (STEREO) era using Advanced Composition Explorer (ACE) Solar Isotope Spectrometer (SIS) and Cosmic Ray Isotope Spectrometer (ULEIS), Energetic Particles: Acceleration, Composition and Transport (EPACT) onboard Wind, and the STEREO-A (Ahead) and -B (Behind) Low-Energy Telescope (LET) and Suprathermal Ion Telescope (SIT) instruments, taking a large number of snapshots covering the temporal evolution of the event. We find large differences in the spectra of the ions after the main flux enhancement in terms of the grouping of similar species, but also in terms of the location of the instruments. Although it is somewhat less noticeable than in the case of the temporal evolution of protons (Doran and Dalla, 2016), we observe a wave-like pattern traveling through the heavy ion spectra from the highest energies to the lowest, creating an "arch" structure that later straightens into a power law after 18 to 24 hours.

During solar flares and coronal mass ejections, solar energetic particles (SEPs) may be released into the interplanetary medium and near-Earth locations. The energy spectra of SEP events at 1 AU are typically averaged over the entire event or studied in a few snapshots. In this paper we analyze the time evolution of the energy spectra of four large selected SEP events using a large number of snapshots. We use a multi-spacecraft and multi-instrument approach for the observations, obtained over a wide SEP energy range. We find large differences in the spectra at the beginning of the events as measured by different instruments. We show that over time, a wave-like structure is observed traveling through the spectra from the highest energies to the lowest energies, creating an "arch" shape which then straightens into a power law later in the event, after times of the order of 10 hours. We discuss the processes that determine SEP intensities and their role in shaping the spectral time evolution.