No abstract

No abstract

The synthesis of Co-NPs and Mn-NPs by microwave-induced decomposition of the metal carbonyls Co(2)(CO)(8) and Mn(2)(CO)(10), respectively, yields smaller and better separated particles in the functionalized IL 1-methyl-3-(3-carboxyethyl)-imidazolium tetrafluoroborate [EmimCO(2)H][BF(4)] (1.6 ± 0.3 nm and 4.3 ± 1.0 nm, respectively) than in the non-functionalized IL 1-n-butyl-3-methylimidazolium tetrafluoroborate [Bmim][BF(4)]. The particles are stable in the absence of capping ligands (surfactants) for more than six months although some variation in particle size could be observed by TEM.

No abstract

No abstract