Three‐dimensional structures of colloidal particles (see Figure for an assembly of polystyrene particles) have been constructed on a water surface rather than on a planar substrate. This method can be used to generate colloidal particles three‐dimensionally irrespective of their size, and if a generated colloidal opal structure is infiltrated by semiconducting materials it could be used for a large range of optical applications.
We report on efficient and fast hybrid photorefractive polymer sensitized with cadmium selenide ͑CdSe͒ quantum dots. The surface of the quantum dots was treated with 4-methylbenzenethiol. This surfactant is responsible for efficient photoinduced charge generation in the composite, leading to fast grating build-up times of 100 ms and below. Overmodulation of the diffraction efficiency was observed at an applied field of 60 V / m.
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