A new type of polymeric hybrid coating is created by layer‐by‐layer deposition of polyelectrolyte multilayers (PEM) onto nano‐patterned polymer brushes (NPB). The PEM is a hydrogen‐bonded multilayer consisting of poly(acrylic acid) and poly(acrylamide) and the NPB is derived from a surface reactive rod‐coil block copolymer, polystyrene‐block‐poly[3‐(triethoxysilyl)propylisocyanate]. The thickness of the PEM coating is optimized with respect to the height of the NPB mounds, to yield PEM/NPB hybrid coatings with unique nano‐embossed or nano‐porous structures that can be interchangeable by heating and moisture annealing. The hybrid coating is patternable by the micro‐contact printing method. The results demonstrate that the combination of surface‐bound, hydrophobic NPB layer with hydrophilic PEM films at the nanoscopic level offers a new organic hybrid coating with novel surface properties.

No abstract