Aus den Dioximen (I) entstehen unter der Einwirkung von Tosylchlorid in siedendem Dioxan durch eine Beckmann‐ Umlagerung 2. Ordnung die Dicyandiamine (II) (H‐NMR‐Spektren), daneben auch geringe Mengen der N‐Tosyl‐Derivate (Ausbeute 7‐11%).
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