It was found that the reactions of arylamines with 3-bromocyclohexene afforded hydrocarbazole compounds in 64--78% yields. A modified procedure for the synthesis of antitumor alkaloid ellipticine was proposed.
A Facile Method for the Synthesis of 3,1-Benzoxazines from N-Acyl-2-(alk-2-enyl)anilines.-Electrophilic addition of HCl or Br 2 to N-acylated o-alkenylanilines proceeds with oxazine ring closure to furnish the spirocyclic benzoxazines in excellent yields, irrespective of geometry or substitution pattern around the double bond.-(GATAULLIN, R. R.; AFONKIN, I. S.; FATYKHOV, A. A.; SPIRIKHIN, L. V.; TAL'VINSKII, E. V.; ABDRAKHMANOV, I. B.; Russ.
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