This discussion of esterification covers both the theoretical and practical implications of the technology. The kinetics and mechanism of esterification of carboxylic acids with alcohols are reviewed, along with factors affecting and methods for bringing about the completion of reaction. Several technical examples of esterification are given to demonstrate how the theory is applied. These examples include discussions of batch, continuous, and vapor‐phase processes. Methods for synthesizing esters from other compounds, such as acid anhydrides, acid chlorides, amides, nitriles, unsaturated hydrocarbons, ethers, aldehydes, and ketones are outlined. Numerous references and techniques are described. The process of esterification is also approached from the aspect of physical properties and characteristics. For example, a discussion on the synthesis of low, medium, and high boiling esters is given. Also, esterification techniques regarding difficulty esterifiable acids and ester interchange are described.

Batch Esterification Continuous Esterification Vapor‐Phase Esterification Esterification of Other Compounds Technical Preparation of Esters Ester Interchange