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It is a matter of considerable practical importance to recognize metastable, potentially hazardous chemical compositions so that suitable thermal hazard management means can be provided as a part of process safety management.This communication is a report on our evaluation of the oxygen balance criterion as a screening technique for thermal hazard assessment.

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This review is intended to provide informatin so as to decrease likelihood that explosive silver compositions are formed by inadvertence: silver azide, silver fulminate, silver nitride, and silver nitrate.