A new method of preparation and the properties (solubility, aggregation, spectralluminescent properties, singlet oxygen and photobleaching quantum yields) of non-metal 2,3,9,10,16,17,23,24-octacarboxyphthalocyanine are reported. The influence of ionization state on photophysicochemical properties of this dye is also presented.
Three new substituted manganese phthalocyanines (PcMns), wich are water-soluble, have been synthesized with good yields (70–80%) and high purity. Pyridiniummethyl- and cholinylsubstituted phthalocyanines have been obtained from the chloromethylsubstituted PcMns , while octacarboxysubstituted complex has been synthesized from metal-free octacarboxyphthalocyanine tetraanhydride. Compounds were characterized by elemental analysis and mass, IR and UV-vis spectroscopy. In general, coordination chemistry of the compounds studied is similar to this one of liposoluble PcMns but some new findings have been obtained. Three coordination forms — PcMn ( II ), PcMn ( III ) X ( X = Cl -, OAc -, …) and [ LPcMn ( III )]2 O ( L = Py , Et 3 N , …) have been obtained for all the new compounds. The equilibrium between three electronic isomers — Pc+• Mn ( I ) × L , PcMn ( II ) × nL , (n = 1, 2) and Pc-• Mn ( III ) × 2 L has been observed in PcMn aqueous solutions upon the addition of organic bases L ( Py , Et 3 N , …).
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.