The anions in the title, n = 1-6, have been conclusively characterised in solution by '9F, 75As, and 121Sb n.m.r. spectroscopy and, for n = 1-5, shown to be stable with respect to fluorine redistribution reactions.Several salts containing halogenofluoroanions of group 5 elements have been isolated; thus SbX2F4', X = C11 or Br,2 and SbX4F2-, X T C1,3 have been prepared and assigned cis octahedral structures on the basis of vibrational spectroscopy. Furthermore Kolditz and Krause4 claim to have obtained tetra-alkylammonium salts of SbCIFS-, AsC1F5-, AsC12F4-,

The 1:1 inclusion compounds of cholic acid with methanol (C24H40O5.CH4O), ethanol (C24H40O5.C2H6O) and 1-propanol (C24H40O5.C3H8O) crystallize in the P2(1)2(1)2(1) space group with unit-cell dimensions at 293 K: a = 15.198 (6), b = 11.625 (7), c = 14.560 (9) A; a = 14.653 (7), b = 11.739 (4), c = 15.045 (2) A; and a = 15.026 (2), b = 11.864 (9), c = 14.951 (4) A; Z = 4. The structures were solved using direct methods. Full-matrix least-squares refinement reduced the conventional R factor to values of 0.109, 0.066 and 0.071, respectively. The alcohol molecules are contained in cavities created by the cholic acid molecules and are involved in the hydrogen-bonding scheme consisting of five unique hydrogen bonds. Statistical disorder is observed for the ethanol and 1-propanol molecules.