An explanation of the unique nonbiofouling properties of polyzwitterions (PZ) is proposed [in this paper, the term "polyzwitterion" is preferred to "polybetain"]. The existence of an osmotic component of the driving force of the antipolyelectrolyte effect (APE) and the parameters governing this phenomenon are quantitatively established. The correlation between this effect, which is specific of PZ only, and the PZ nonbiofouling properties is grounded.

The efficiency of iodobenzene 1,1‐diacetate or (diacetoxyiodo)benzene (DAIB) as a thermo‐ and sono‐initiator of methyl methacrylate (MMA) in radical bulk polymerization is tested. The polymerization kinetics and molecular‐mass characteristics support an assumption for a combined polymerization mechanism including a classical bimolecular termination with chain transfer reaction and iniferter quasi‐living polymerization. In addition to the equilibrium formation and degradation of the ‘dormant’ polymer ends, other possible decomposition reactions of the hypervalent iodine bond are the probable reason for the deviation of this polymerization from the iniferter polymerization mechanism. These reactions bear some similarity to the two‐step addition–fragmentation chain transfer mechanism of controlled radical polymerization. The application of the poly(MMA) obtained as a macroinitiator is evidence of ‘dormant’ chain end formation.© 2001 Society of Chemical Industry

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The precipitation temperature (Tpr) value of aqueous poly(dimethylamino‐ethoxyacryloyl‐propylsulphonate) (PDMAPS) solutions decreases with the rise of electric field intensity both in the absence and in the presence of a low molecular salt. This electrostimulated Tpr shift is explained qualitatively by means of the model taking into account both the dominating intermacromolecular dipole‐dipole interaction and the dipole cluster formation.