Mechanochemistry of inorganic solids is a well-established field. In the last decade mechanical treatment has become increasingly popular as a method for achieving selective and "greener" syntheses also in organic systems. New groups and researchers enter the field of mechanochemistry, often re-discovering many of the previously known facts and effects, while at the same time neglecting other important concepts. The author of this contribution has long been involved in mechanochemical research in both inorganic and organic systems. The aim of this contribution is to provide an overview of the basic concepts of mechanochemistry in relation to inorganic and organic systems.
Crystals on the move: If they are subjected to a strong light stimulus, crystals of the cobalt coordination compound [Co(NH3)5(NO2)]Cl(NO3) undergo sudden jumps and leap over distances 10(2)-10(5) times their own size to release the strain that accumulates in their interior. The first quantitative kinematic analysis of this phenomenon is reported. The observed effect could be employed for actuation on the macroscopic scale.
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