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A general, efficient approach for the synthesis of fluorocarbon iodides and di-iodides bearing hydrocarbon groups is described and the synthetic utility of these new systems is demonstrated in reactions with thiols.

New Fluorocarbon Iodides.-A general and efficient methodology for the synthesis of new fluorocarbon iodides bearing hydrocarbon end-groups is described and the synthetic utility of these new systems in reactions with thiols is demonstrated. -(CHAMBERS, RICHARD D.; COOPER, JULIAN A.; COPIN, ELODIE; SANDFORD, GRAHAM; Chem. Commun. (Cambridge) (2001) 23, 2428-2429; Dep. Chem., Univ. Durham, Durham DH1 3LE, UK; EN)