Arrowroot starch membrane-modified glassy carbon electrode were constructed for the determination of uric acid. The membrane consist of arrowroot starch, polyvinyl alcohol, uric acid, and crosslinker. The crosslinker used was sodium tripolyphosphate, citric acid, and glutaraldehyde. Carbon material was added to increase the sensitivity. The composition of membrane influences the electrodes sensitivity. The best composition of arrowroot starch membrane is UA1 using 0.1% uric acid in membrane and STPP as crosslinker. The linearity concentration, sensitivity, and detection limit were 100-500 µM, 0.0509 A/M and 76 µM, respectively.
Molecularly Imprinted Polymer (MIP) dari poli vinil alkohol (PVA)-Fe3O4 telah dikembangkan sebagai reseptor pada sensor kimia untuk diazinon dan monosodium glutamat (MSG). MIP dibuat dari PVA menggunakan glutaraldehid sebagai crosslinker dan asam sitrat sebagai katalis. Reseptor adalah suatu template yang disesuaikan dengan sensornya; template diazinon untuk sensor diazinon dan template MSG untuk sensor MSG. Reseptor MIP PVA-Fe3O4 dilapiskan pada permukaan elektroda karbon tipe screen printed (SPE). Pada penelitian ini, telah dipelajari pengaruh asam sitrat dan glutaraldehid terhadap pembentukan MIP. Dipelajari juga pengaruh kadar diazinon dan MSG terhadap kinerja masing-masing sensor. Kadar diazinon dalam reseptor yang dipelajari adalah 0,01; 0,02; dan 0,03%, sedangkan kadar MSG adalah 0,5; 0,9; dan 4,5%. Berdasarkan spektrum FTIR, hasil penelitian menunjukkan bahwa pada MIP PVA-glutaraldehid terdapat gugus fungsi C-O yang menunjukkan adanya ikatan silang antara PVA dan glutaraldehid; sedangkan pada MIP PVA-asam sitrat tidak menunjukkan adanya gugus fungsi tersebut. Kinerja sensor diazinon dan MSG dipengaruhi oleh kadar/jumlah template dalam reseptor. Kinerja optimum sensor dihasilkan pada membran reseptor masing-masing adalah diazinon 0,02 %, dan MSG 0,5 %. Kepekaan sensor diazinon adalah 33,8 mV/dekade pada pH 2, dalam buffer fosfat-KCl, rentang konsentrasi 10-5-10-12 M, dan waktu respon 150 detik. Kepekaan sensor MSG adalah 33,25 mV/dekade pada kisaran konsentrasi 10-5-10-1 M, dalam pH 5 dan waktu respon 180 detik.
A new tube type Pb2+ sensor made from two types of mixtures, namely clay-PbI2 and chitosan-PbI2 were prepared. An electromotive force (EMF) with Ag/AgCl as the reference electrode was used as the output signal. The highest performance of the Pb2+ sensor from clay-PbI2 was obtained at Pb2+ solutions in HNO3 and pH 3 with sensor sensitivity of 20.67 mV/decade. The highest performance of the Pb2+ sensor from chitosan-PbI2 was obtained at Pb2+ solutions in demineralized water with sensor sensitivity of 32.49 mV / decade. Application of the two sensors on several commercial herbal samples resulted in an average recovery of 85.62% and 94.10% for sensor from chitosan-PbI2 and clay-PbI2, respectively
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