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Synthesis and catalytic activity of new, water-soluble mono-and dinuclear ruthenium(II) complexes containing 1,3,5-triaza-7-phosphaadamantane: study of the effect of the visible light.

Media. -A wide variety of glycosyl cyanides such as (I) are converted into the corresponding formamide derivatives in water or water/NMP mixtures as the solvent. O-Acetyl, O-benzoyl, O-benzyl protecting groups, double bonds, anomeric bromide, and azide substituents are compatible to this reaction conditions. -(MISRA, A. K.; BOKOR, E.; KUN, S.; BOLYOG-NAGY, E.; KATHO, A.; JOO, F.; SOMSAK*, L.; Tetrahedron Lett. 56 (2015) 44, 5995-5998, http://dx.