Anti-crack performance of concrete with phosphorus slag and fly ash singly and compositely added is investigated in terms of physical performance, hydration heat, dry shrinkage and creep. Index K is introduced to evaluate the crack resistance of phosphorus slag concrete. Results show that the strength of phosphorus slag concrete increases with the increase of fineness, and when surface specific area is greater than 300 m 2 /kg, the tendency slows down. Strength decreases with phosphorus slag content increasing and there is an optimal content existing between 30% and 50%. Both phosphorus slag and fly ash have obvious effect on elongating time setting, reducing hydration heat to a large extent and increasing creep value. Crack resistance of phosphorus slag concrete is divided into three stages, namely early hazardous stage, growth stage and later mature stage. With microstructure analysis, mechanism of effect of phosphorus slag on concrete performances and P and F on cement hydration is explored. It is concluded after comprehensive evaluation that the crack resistance of phosphorus slag concrete is approximate to, even to some extent better than that of fly ash concrete.

Hydration characteristics of Portland cement paste with phosphorus slag powder incorporated and hydration kinetics was investigated with SEM, X-ray diffraction, DTA-TG and calorimeter Ⅱ80. Results showed that phosphorus slag powder could reduce total amount of hydration products yet had little influence on the type of hydration products. The total amount of heat of hydration was decreased by 49.11% and the final setting was postponed by 2.28 h when phosphorus slag powder substituted 35% Portland cement by mass. The accelerating stage of this composite paste was controlled by catalysis, decreasing stage controlled by both catalysis and diffusion while stabilizing stage by diffusion alone. Hydration resistance and activation energy were reduced and hydration speed was accelerated.

The properties and mechanism of concrete under water leakage corrosion were studied in terms of the dissolution of calcium oxide and silicon oxide from concrete and the variation of pH value of permeate water. The experimental results show that the amount of calcium oxide and silicon oxide dissolved from per cubic meter of concrete gradually decrease with penetration time and ultimately stabilize at a certain value. The pH value of permeate water descend along with penetration time. The durability of concrete under leakage corrosion was analyzed by a formula fitted on the dissolved amount of calcium oxide.

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