In China, excessive nitrogen fertilizer application in sweet maize fields contributes to greenhouse gas emissions. This study used maize straw (MS), cow dung (CD), biogas residue (BR), and straw-based biochar (CB) to substitute the mineral nitrogen fertilizer at 20% and 50% ratios in the Pearl River Delta in China. In comparison with a conventional amount of mineral nitrogen fertilizer (CK), the soil organic carbon (SOC) storages of the different treatments increased by 6.5–183.0%. The CB treatment significantly improved the inert organic carbon pool in the soil, while other types of organic materials promoted the formation of activated carbon pools. The treatments increased the soil carbon pool management index by 21.1–111.0% compared to the CK. Moreover, the CB treatments increased the soil carbon sequestration index by 78.3% and 155.8% compared to the CK. In general, substituting the mineral N fertilizer with BR, CB, and CD could improve the SOC accumulation in sweet maize farmland in South China. The CB at the high substitution level was the best measure for stabilizing carbon sequestration in the sweet maize cropping system. This experiment provides valuable information for ensuring the clean production of sweet maize in a typical subtropical area in East Asia.

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