The synthesis, characterization, photophysical and redox properties of a dinuclear complex Zn 2 (AMOX) 4 (AMOX = 4-bromo-N,N′-diphenylbenzamidinate N-oxide) are highlighted. This compound is a first example of a novel class of aggregation-induced emission (AIE) materials. Noticeably, solution-processed white-green organic light-emitting diodes were fabricated using this complex as dopant in a co-host matrix in the [a] 4324 gands. This distinction indicates that the energy of the LUMO can be fine-tuned by modifying the C-aryl substituents with EW/ED groups. The TD-DFT calculations for 1 ( Figure S10, Table Eur.

Herein, we demonstrate the improvement in performance of inverted organic solar cells fabricated with an Ag-nanoparticle (Np) modified ZnO-electron transport layer. Ag NP incorporation into the ZnO layer increases light harvesting efficiency of the solar device which untimely improves Jsc of the device. As a result, power conversion efficiency (PCE) of ZnO + Ag Np buffer layer based (ITO/ZnO:Ag NP/P3HT: PCBM/MoO3/Ag) device reaches 3.02% which is 27% higher than ITO/ZnO/P3HT: PCBM/MoO3/Ag device and 55.6% higher than the electron transfer layer(ETL) free (ITO/P3HT: PCBM/MoO3/Ag) control device.