The potential biosorbent of stinky bean peel (Parkia speciosa) (SBP) was investigated for azo dye Procion Red Mx-5B removal due to their accessibility, economically feasible, easy pretreatment, and non-toxic. This study aims to determine the effect of chemically modified of the SBP, that a massive agricultural waste in Sarawak, to enhance its ability during adsorption of dye. The biosorbent used was dried, ground, and sieved through 600 µm sieve to obtain a similar average size. Impregnation with some chemicals was performed by using ZnCl2, K2CO3, H2SO4 and NaOH for 24 h. The Freundlich, Langmuir, and Temkin techniques were examined to calculate the isotherm data. The result showed that the sorption capacity of the SBP was improved by ZnCl2 modification. The equilibrium data were fitted with the Freundlich model, while the kinetic study was fitted with the pseudo-second-order kinetic model. Further, it was concluded that dyes uptake by biosorbent was based mainly on the role of carboxyl and a hydroxyl group.

Abstract. Diagrid system has gained a wide acceptance in the design of tall buildings due to its many advantages including its high structural efficiency in resisting both gravity and lateral loads. Most diagrid structures that had been studied have full triangulated members from the ground level to the top of the buildings where comparison in the effectiveness in minimizing the lateral displacement was often made between structures with full diagrid, frame and outrigger system. Nevertheless, no study has been performed on the effectiveness of the diagrid that is constructed above a frame system. The objective of this research is to understand the behavior of the lateral displacement and shear lag effect due to wind load when the diagrid structure is constructed above a frame. Models of sixty storey buildings were analyzed by using Staad.Pro software. The level where the diagrid members started and the spacing of vertical base columns of the frame were altered. The lateral displacement and shear lag effect resembled closely of those of the model of full diagrid when the diagrid was started at level 3, and the vertical base columns were uniformly spaced at 6 metres.