Two
novel layer structure compounds, Cs
2
HgSb
4
S
8
and Cs
2
Hg
2
Sb
2
Se
6
, were synthesized in organic solvent under solvothermal conditions.
The Cs
2
HgSb
4
S
8
is formed of [HgSb
4
S
8
]
2–
ribbons and S atoms by
corner sharing. The Cs
2
Hg
2
Sb
2
Se
6
is made up of [SbHg
2
Se
6
]
5–
ribbon and disorder trigonal-pyramidal SbSe
3
by sharing
μ
3
-Se. These compounds are characterized by single-crystal
X-ray diffraction, powder X-ray diffraction, solid-state optical absorption
spectra, and so on.
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