Environmental health concerns over conventional chromium based surface treatments on aluminium substrates are well known. Current research efforts have concentrated on developing protective technologies for multiple applications. Such properties would enable manufacturers to address both corrosion and bacterial threats in areas such as fuel tanks and delivery systems.The present study explores the anticorrosion properties of 1,2-dihydro 1, 2, 4, 5 tetrazine-3, 6-dicarboxylic acid (H2DCTZ) on a copper rich aerospace aluminum alloy (AA 2024-T3).Furthermore the antimicrobial activity of the tetrazine is evaluated against Gram-positive and Gram-negative bacteria, both capable of inducing corrosion. The protective action of the tetrazine was investigated at different concentrations in a chloride ion rich environment (3.5% (w/v) NaCl) utilising electrochemical impedance spectroscopy (EIS). Results over a 72 hour period proved that an optimum concentration was 500 ppm. FTIR and SEM elemental mapping of the surface confirmed the nitrogen rich tetrazine affinity for the copper rich intermetallic sites, through coordinate bonds, which delayed corrosion onset and reduced pit formation. Moderate antibacterial tetrazine activity was observed against Escherichia coli and 100% efficacy against Staphylococcus aureus at 250 ppm was achieved. The damage of the bacterial cell envelope at the critical concentrations (250 ppm) is proposed as a possible mechanism for antibacterial action.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
customersupport@researchsolutions.com
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.