A low viscosity, hydrophobic eutectic solvent based on trioctylphosphine oxide (TOPO) has been developed and characterized, and its use as an extractant demonstrated for liquid−liquid separation of uranyl nitrate from aqueous acid. This strategy of liquefying the active extracting agent as a eutectic liquid produced liquids that contain an intrinsically high concentration of TOPO (ca. 80 wt %, 1.875 mol L −1 at χ TOPO = 0.50) and renders the use of an organic (hydrocarbon) diluent redundant.
This paper computes the quadratic Witt groups (the Wall L-groups) of the polynomial ring Z[t] and the integral group ring of the infinite dihedral group, with various involutions. We show that some of these groups are infinite direct sums of cyclic groups of order 2 and 4. The techniques used are quadratic linking forms over Z[t] and Arf invariants.
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