Allende meteorite Ca-Al rich inclusions U-Pb age 26 Al/ 27 Al ratio The precise knowledge of the initial 26 Al/ 27 Al ratio [(26 Al/ 27 Al) 0 ] is crucial if we are to use the very first solid objects formed in our Solar System, calcium-aluminum-rich inclusions (CAIs) as the "time zero" age-anchor and guide future work with other short-lived radio-chronometers in the early Solar System, as well as determining the inventory of heat budgets from radioactivities for early planetary differentiation. New high-precision multicollector inductively-coupled plasma mass spectrometry (MC-ICP-MS) measurements of 27 Al/ 24 Mg ratios and Mg-isotopic compositions of nine whole-rock CAIs (six mineralogically characterized fragments and three microdrilled inclusions) from the CV carbonaceous chondrite, Allende yield a well-defined 26 Al-26 Mg fossil isochron with an (26 Al/ 27 Al) 0 of (5.23± 0.13)× 10 − 5. Internal mineral isochrons obtained for three of these CAIs (A44A, AJEF, and A43) are consistent with the whole-rock CAI isochron. The mineral isochron of AJEF with (26 Al/ 27 Al) 0 =(4.96± 0.25) × 10 − 5 , anchored to our precisely determined absolute 207 Pb-206 Pb age of 4567.60 ± 0.36 Ma for the same mineral separates, reinstate the "canonical" (26 Al/ 27 Al) 0 of 5 × 10 − 5 for the early Solar System. The uncertainty in (26 Al/ 27 Al) 0 corresponds to a maximum time span of ±20 Ka (thousand years), suggesting that the Allende CAI formation events were culminated within this time span. Although all Allende CAIs studied experienced multistage formation history, including melting and evaporation in the solar nebula and post-crystallization alteration likely on the asteroidal parent body, the 26 Al-26 Mg and U-Pb-isotopic systematics of the mineral separates and bulk CAIs behaved largely as closed-system since their formation. Our data do not support the "supra-canonical" 26 Al/ 27 Al ratio of individual minerals or their mixtures in CV CAIs, suggesting that the supracanonical 26 Al/ 27 Al ratio in the CV CAIs may have resulted from post-crystallization inter-mineral redistribution of Mg isotopes within an individual inclusion. This redistribution must be volumetrically minor in order to satisfy the mass balance of the precisely defined bulk CAI and bulk mineral data obtained by MC-ICP-MS. The radiogenic 208 Pb⁎/ 206 Pb⁎ ratio obtained as a by-product from the Pb-Pb age dating is used to estimate timeintegrated 232 Th/ 238 U ratio (κ value) of CAIs. Limited κ variations among the minerals within a single CAI, contrasted by much larger variations among the bulk CAIs, suggest Th/U fractionation occurred prior to crystallization of igneous CAIs. If interpreted as primordial heterogeneity, the κ value can be used to calculate the mean age of the interstellar dust from which the CAIs condensed.
In order to check the heterogeneity of the CI chondrites and determine the average composition of this group of meteorites, we analyzed a series of 6 large chips (weighing between 0.6 and 1.2 g) of Orgueil prepared from 5 different stones. In addition, one sample from each of Ivuna and Alais were analyzed. Although the sizes of the chips used in this study were "large", our results show evidence for minor chemical heterogeneity in Orgueil, particularly for alkali elements and U. After removal of one outlier sample, the spread of the results is considerably reduced. For most of the 46 elements analyzed in this study, the average composition calculated for Orgueil is in very good agreement with previous CI estimates. This average, obtained with a "large" mass of samples, is analytically homogeneous and is suitable for normalization purposes.Finally, the Cu and Zn isotopic ratios are homogeneously distributed within the CI parent body with a spread of less than 100 ppm per atomic mass unit (amu).
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