Molecules with high two-photon absorption (TPA)

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Nonlinear optical phase conjugation by degenerate four-wave mixing (DFWM) is an important technique with applications in many fields of science and technology. Phase conjugation by Degenerate four-wave mixing is observed in Disperse Orange-25 dye doped in Polymethyl methacrylate – metacrylic acid (PMMA-MA) polymer film under low-power, continuous-wave laser irradiation. A maximum phase conjugate efficiency of 0.22% has been obtained for probe beam intensity at 0.11 W/cm2. Phase conjugation is observed for both parallel- and orthogonally-polarized probe and pump beams. The maximum PC reflectivity is achieved when the angle between probe and forward pump beam is 7 degrees. The effects of dye concentration, intensity of backward, forward pump and inter beam angle between probe and forward pump beam on phase conjugation reflectivity are also studied. PC signal strength first increases and then decreases. PC reflectivity is increased by increasing the intensity of the backward and forward pump beam. The polarization and intensity profile are verified to be preserved in the conjugate signal. The predominant phase conjugation signal is attributed to the facts that reverse saturable absorption and large third order susceptibility of the dye molecules.

The materials with an ability of self-focusing/defocusing through their light intensitydependent refractive index and phase shift properties are potential candidates for all-optical photonic devices. Several organic materials including dye-doped polymer films are attracting many researchers due to their advantages in terms of enhanced efficiency, and acceptable mechanical properties to fabricate useful devices. In this paper, we have reported the nonlinear optical properties like nonlinear absorption and nonlinear refraction of an organic dye Disperse Yellow - 7 (DY-7) doped in Polymethyl methacrylate-methacrylic acid (PMMA-MA) polymer matrix using open aperture and closed aperture Z-scan experimental methods by means of low power continuous wave (CW) laser beam. The optical limiting properties of these films are also studied using Type 1 and Type 2 configurations at different input powers using continuous wave (CW) laser beams of 532 nm wavelength. The nonlinear refractive index n2, nonlinear absorption coefficient β, changes in refractive index with input intensity, and the magnitude of third-order optical nonlinearity of the dye-doped film are experimentally determined. The sample is tested for optical power limiting in which the input limiting threshold and saturated output power level for both type 1 and type 2 optical limiting configurations are recorded. DY-7 dye-doped in PMMA-MA polymer film has shown saturation absorption at lower input irradiance and reverse saturation absorption at higher input irradiance along with thermal nonlinearity and hence found to be a potential candidate for the third harmonic property based photonic devices.