This paper reports a comparative kinetic investigation of the overall reduction of NO in the presence of CO or H 2 over supported Pt-, Rh-and Pd-based catalysts. Different activity sequences have been established for the NO+H 2 reaction . It was found that both reactions differ from the rate determining step usually ascribed to the dissociation of chemisorbed NO molecules. The rate enhancement observed for the NO+H 2 reaction has been mainly related to the involvement of a dissociation step of chemisorbed NO molecules assisted by adjacent chemisorbed H atoms. The calculation of the kinetic and thermodynamic constants from steadystate rate measurements and subsequent comparisons show that Pd and Rh are predominantly covered by chemisorbed NO molecules in our operating conditions which could explain either changes in activity or in selectivity with the lack of ammonia formation on Rh/Al 2 O 3 during the NO+H 2 reaction. Interestingly, Pd and Rh exhibit similar selectivity behaviour towards the production of nitrous oxide (N 2 O) irrespective of the nature of the reducing agent (CO or H 2 ). A weak partial pressure dependency of the selectivity is observed which can be related to the predominant formation of N 2 via a reaction between chemisorbed NO molecules and N atoms, while over Pt-based catalysts the associative desorption of two adjacent N atoms would occur simultaneously. Such tendencies are still observed under lean conditions in the presence of an excess of oxygen. However, a detrimental effect is observed on the selectivity with an enhancement of the competitive H 2 +O 2 reaction, and on the activity behaviour with a strong oxygen inhibiting effect on the rate of NO conversion, particularly on Rh.

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