Biomass waste, including municipal solid waste (MSW), contains lignocellulosic-containing fiber components that are not readily available as substrates for anaerobic digestion due to the physical shielding of cellulose imparted by the nondigestible lignin. Consequently, a substantial portion of the potentially available carbon is not converted to methane and the incompletely digested residues from anaerobic digestion generally require additional processing prior to their return to the environment. We investigated and developed steam pressure disruption as a treatment step to render lignocellulosic-rich biomass more digestible and as a means for increasing methane energy recovery. The rapid depressurization after steam heating (240 degrees C, 5 min.) of the nondigested residues following a 30-day primary digestion of MSW caused a visible disruption of fibers and release of soluble organic components. The disrupted material, after reinoculation, provided a rapid burst in methane production at rates double those observed in the initial digestion. This secondary digestion proceeded without a lag phase in gas production, provided approximately 40% additional methane yields, and was accompanied by a approximately 40% increase in volatile solids reduction. The secondary digestate was found to be enriched in lignin and significantly depleted in cellulose and hemi-cellulose components when compared to primary digestate. Thus, steam pressure disruption treatment rendered lignocellulosic substrates readily accessible to anaerobic digestion bacteria and improved both the kinetics of biogas production and the overall methane yield from MSW. Steam pressure disruption is central to a new anaerobic digestion process approach including sequential digestion stages and integrated energy recovery, to improve process yields, provide cogenerated energy for process needs, and to provide effective reuse and recycling of waste biomass materials.
Some oil pump station design layouts may contain multiple dead-legs. During the transportation of heavy crude through the pump station, these dead-legs will be filled with this crude. When a light crude batch is introduced next into the pipeline, following the heavy crude ahead, two phenomena will occur. First, contamination between batches at the interface of the two crudes will occur due to axial turbulent diffusion along the length of the pipeline itself. Second, as the light crude flows through the pump station and passes by each dead-leg containing still heavy crude from the preceding batch, the heavy crude trapped in these dead-legs will start to drain out into the passing light crude in the main run. This causes further contamination and spreading of the mixing zone between the two batches. These two different sources of contamination are addressed in this paper with the objective of accurately quantifying the extent of the contamination, with particular emphasis on the second phenomenon which could cause appreciable contamination particularly for large size and number of these dead-legs. A computational fluid dynamics (CFD) model has been developed to quantify the drainage rate of the contaminating crude into the main stream and its impact on widening the mixed zone (contamination spread) between the two batches. Two drainage mechanisms of the heavy crude in the dead-legs into the main stream of the light crude have been identified and quantified. The initial phase is a gravity-current-induced outflow of the initially stagnant fluid in the dead-leg, followed by a subsequent draining mechanism primarily induced by turbulent mixing and diffusion at the mouth of the dead-leg penetrating slightly into the dead-leg. It was found that the second mechanism takes a much longer time to drain the first, and that the break point in time where drainage switches from a predominantly gravity current to a turbulent diffusion appears to be at a specific time normalized with respect to the length of the dead-leg and the gravity current speed. The results show a consistent trend with actual interface contamination data obtained from the Keystone 2982 km pipeline from Hardisty (Canada) to the Patoka Terminal (U.S.A.).
Construction of the Borsig waste heat recovery system at NOVA’s Clearwater Compressor Station is now complete. Initial operation of the system has been very encouraging. This paper is an update on an earlier paper entitled “Pipeline Compressor Station with Waste Heat Recovery” by G. M. Holldorff, A. R. Hladun and S. A. Dunn. The process cycle including main components and control functions will be reviewed and their performance evaluated. Operating experience to date is also presented. In emphasizing safety, NOVA has instituted unique operating and maintenance procedures to this system. These procedures are also outlined.
Invariably, oil pump station piping layouts may contain multiple dead-legs brought about by closed valves at one end of side branches, while flows continue through the main runs. During the transportation of heavy crude through the pump station, these dead-legs will be filled with this crude. When a light crude batch is introduced next into the pipeline, following the heavy crude ahead, two phenomena will occur. First, contamination between batches at the interface of the two crudes will occur due to axial turbulent diffusion along the length of the pipeline itself. Second, as the light crude flows through the pump station, and passes by each dead-leg containing residual heavy crude from the preceding batch, the heavy crude trapped in these dead-legs will start to drain out into the passing light crude in the main run. This causes further contamination and spreading of the mixing zone between the two batches. The second source of contamination, which is addressed in this paper, could cause appreciable contamination particularly for large dead-leg sizes and numbers. A computational fluid dynamics (CFD) model has been developed to quantify the drainage rate of the contaminating crude into the main stream and its impact on widening the mixed zone (contamination spread) between the two batches. Two drainage mechanisms of the heavy crude in the dead-legs into the main stream of the light crude have been identified and quantified. Finally, potential innovations to mitigate contamination due to dead legs are presented and quantified for their respective effectiveness in minimizing the contamination spreads between batches of different crudes.
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