No abstract

However, no such agreement exists with regard to the mechanism of 02 reactions with olefins that lead to allylic hydroperoxides. A cyclic cis process was established by stereochemical studies3 and a large body

No abstract

The structure of a hydrocarbon, 2,6,10,10tetramethyltricyclo [ 7,2,0, 02y7]undec-5-ene (I), obtained by eliminating hydrogen chloride from caryophyllene dihydrochloride, has been determined by the X-ray analysis of its dibromo derivative (11).DURING early investigations into the chemistry of caryophyllene, several workers used the dihydrochloride (111) t as a suitable crystalline derivative. In an effort to elucidate the structure of caryophyllene and unaware of the comref lux (-2 H C I I M e c1 (nI) H ..

No abstract