Seven functionalised N-heterocyclic carbene (NHC) ligands and their corresponding palladium(II) complexes have been synthesised with a triazole moiety as a modular and stable linkage between the catalytic centre and the secondary functional group. The complexes were prepared in good yields and fully characterised by NMR spectroscopy, mass spec- [a]2088 trometry and X-ray crystallography. The complexes are active in the Suzuki-Miyaura cross-coupling reaction, with catalytic activities maintained whatever the triazolyl substituent. This opens the possibility for various functionalisations of NHC-palladium complexes.

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