The ZnII ion in the title compound, [Zn(C9H6NO4)2(H2O)4], is located on an inversion center and is octahedrally coordinated by two 2-(2-oxo-2,3-dihydro-1,3-benzoxazol-3-yl)acetate anions in axial sites and four water molecules in equatorial positions. In the crystal, O—H...O hydrogen bonds between the coordinated water molecules and carbonyl–carboxylate O atoms lead to pleated sheets parallel to (001)
The asymmetric unit of the title compound, C22H18N2O2, contains two independent molecules, which differ in the orientations of the benzyl groups with respect to the planar (r.m.s. deviations of 0.031 and 0.020 Å) quinazoline-2,4-dione skeletons [dihedral angles of 73.97 (4) and 70.07 (4)° in the first molecule and 75.63 (4) and 63.52 (3)° in the second]. The crystal structure is stabilized by weak intermolecular C—H⋯O and C—H⋯π interactions and aromatic π–π stacking interactions [centroid–centroid distance = 3.735 (2) Å].
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