Gregory J. Grant scite author profile

A unique trinuclear cluster containing two short Pt-->Ag dative bonds was prepared and characterized crystallographically. Two monocationic orthometalated Pt(II) complexes containing 2-phenylpyridine and the tridentate ligand 9S3 (1,4,7-trithiacyclononane) exhibit axial sulfur interactions with Pt as well as short dative bonds. The Pt-->Ag dative bonding results in a dramatic shortening of the axial Pt-S distance in each Pt complex cation, relative to the mononuclear Pt complex. Evidence for Pt-Ag interactions in solution is also presented.

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Synthesis and complexation studies of mesocyclic and macrocyclic polythioethers XIV. Crown thioether complexes of palladium(II) and platinum(II)

Grant

Spangler

Setzer

et al. 1996

Inorganica Chimica Acta

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Gregory J. Grant

Heteroleptic platinum(II) complexes with crown thioethers and diimine ligands: the crystal structures of [Pt(9S3)(2,2′-bipy)](PF6)2 and [Pt(9S3)(4,4-dimethyl-2,2′-bipy)](PF6)2·2.5CH3NO2

Cationic Five-Coordinate Pt^II Complexes as Donors in the Formation of Pt→Ag Dative Bonds

Synthesis and complexation studies of mesocyclic and macrocyclic polythioethers XIV. Crown thioether complexes of palladium(II) and platinum(II)

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Gregory J. Grant

Heteroleptic platinum(II) complexes with crown thioethers and diimine ligands: the crystal structures of [Pt(9S3)(2,2′-bipy)](PF6)2 and [Pt(9S3)(4,4-dimethyl-2,2′-bipy)](PF6)2·2.5CH3NO2

Cationic Five-Coordinate PtII Complexes as Donors in the Formation of Pt→Ag Dative Bonds

Synthesis and complexation studies of mesocyclic and macrocyclic polythioethers XIV. Crown thioether complexes of palladium(II) and platinum(II)

Contact Info

Product

Resources

About

Cationic Five-Coordinate Pt^II Complexes as Donors in the Formation of Pt→Ag Dative Bonds