Molecular wheels composed of edge‐shared metal‐ligand coordination octahedra usually feature metal ions that are linked by bridging ligands possessing the same type of donor atoms. Herein we describe heterobridged wheels {Run(μ‐SR)n(μ‐X)n}(CO)2n (R=Trip; n=6, X=Cl, Br; n=8, X=I), which were formed in the reactions between Ru3(CO)12, 2,4,6‐triisopropylbenzenethiol (HSTrip) and HX (X=Cl, Br) or I2. These hexa‐ and octanuclear heterobridged wheels featuring thiolate/halide mixed bridging ligands have all been characterized by X‐ray crystallography as well as spectroscopic means including NMR, IR and ESI‐MS.