No abstract

In the present investigation, a one-step synthesis of hydrochar (HC) supported zero-valent iron (ZVI) was performed through hydrothermal carbonization (HTC) of granatum and ZVI. According to XRD, XPS, and FTIR data, ZVI was evenly distributed on the surface of the hydrochar. In addition, the external ZVI oxide layer and the functional groups present in the hydrochar remained on the surface of the HC/ZVI composites after HTC treatment. The surface area of the HC/ZVI composites was between 31.11 and 44.16 m2/g. These numbers were higher than those obtained for hydrochar (20.36 m2/g) and ZVI (12.14 m2/g) separately. The Pb2+ adsorption capacity of hydrochar and ZVI was 28.64 and 192.44 mg/g, respectively (25 °C, pH = 6.05, Pb2+ concentration of 200 mg/L with 0.05 g HC and 0.01 g ZVI). In addition, the adsorption capacity of the composites was between 49.63 and 88.09 mg/g. The data obtained for Pb2+ removal by the samples used in this experiments fitted well the pseudo-second-order kinetics and Langmuir isotherm models. Therefore, hydrochar may represent a promising supporting material for the synthesis of ZVI composites.

Ibuprofen (IBU), a nonsteroidal anti-inflammatory drug, is one of the most widely used and frequently detected pharmaceuticals and personal care products in water bodies. This study examined the IBU degradation in aquatic solutions via ferric ion activated peroxydisulfate (PDS) coupled with electro-oxidation (EC/Fe3+/PDS). The degradation mechanisms involved three synergistic reactions in the EC/Fe3+/PDS system, including: (1) the electro-oxidation; (2) SO4•− generated from the activation of PDS by ferrous ions formed via cathodic reduction; (3) SO4•− generated from the electron transfer reaction. The radical scavenging experiments indicated that SO4•− and •OH dominated the oxidation process. The effects of the applied current density, PDS concentration, Fe3+ dosage, initial IBU concentration and initial pH as well as inorganic anions and humic acid on the degradation efficiency, were studied, and the degradation process of IBU followed the pseudo-first-order kinetic model. About 99.37% of IBU was removed in 60 min ((Fe3+ concentration) = 2.0 mM, (PDS concentration) = 12 mM, (initial IBU concentration) = 30 mg/L, current density = 15 mA/cm2, initial pH = 3). Finally, seven intermediate compounds were identified and probable IBU degradation pathways in the EC/Fe3+/PDS system were speculated.

New requirements, under the background of new engineering, are put forward for talents training mode and course teaching reform, and the teaching reform on specialized courses is an important link for talents training. The paper, combining with teaching management practice, analyzed and discussed the application of multimode teaching method in water supply and drainage major course teaching.

Abstract. With the continuous development of computer technology, computer-aided design software functions are increasingly perfect and convenient. BIM technology has obvious guiding advantages in the process of architectural design and construction. Based on a basement conversion process as an example in this paper, the core of the BIM modeling software Revit and Navisworks will be used to guide the construction of the project design.