A novel branched polyether surfactant (TPE) was prepared by anion polymerization with different proportions of propylene oxide (PO) and ethylene oxide (EO) using 1,1,2,2‐tetrakis(4‐hydroxyphenyl)ethane as a core. The structures and average molecular weight (Mn) of the TPE were characterized by 1H NMR and GPC. The cloud point was determined by turbidimetry in the presence of inorganic salts. Inorganic salts decreased the cloud point of TPE polyether in the following order: Na2CO3 > Na2SO4 > NaCl > CaCl2 > MgCl2. The effects of inorganic salts (NaCl, MgCl2, CaCl2, and NaSCN) and temperature on the surface activity of TPE in aqueous solution were investigated by surface tension measurements. The surface activity parameters and the thermodynamic parameters were calculated from surface tension data. Similar to the effect of increasing temperature, the salting‐out inorganic salts such as NaCl, MgCl2, and CaCl2 favor the micellization and increase the maximum surface excess concentration, while the salting‐in NaSCN has the opposite effect. The influence of NaCl on the morphology of micelles was investigated by TEM. The micellization is entropy‐driven at low temperature and enthalpy‐driven at higher temperature. The TPE polyether has large surface activity and can be used as a demulsifier to break up crude oil emulsions.
FengYun-3E (FY3E), launched on 5 July 2021, is one of China’s polar-orbiting meteorological satellite series. The GNOS II onboard FY3E is an operational GNSS remote sensor that for the first time combines GNSS radio occultation (GNSS RO) and GNSS reflectometry (GNSS-R). It has eight reflection channels that can track eight specular points at the same time, receiving reflected signals from multiple GNSS systems, including GPS, BeiDou and Galileo. The basic GNSS-R output generated by GNOS II is a 122 × 20 non-uniform delay-Doppler map whose high resolution portion captures more information near the specular point. This paper introduces the GNSS-R aspect of the FengYun-3E GNOS II, including the instrument, power calibration and wind speed retrieval algorithm. Preliminary validation results for its first four months of data are also presented. After preliminary quality control, the overall wind speed error is less than 2 m/s at wind speeds below 20 m/s for data from both GPS satellites and BeiDou satellites when compared to the ECMWF reanalysis winds.
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