Mechanoresponsive
luminescent materials have attracted widespread
attention for their potential applications, especially for these behaving
pressure-induced emission enhancement (PIEE). Designing and seeking
systems with high-efficiency PIEE are desirable and crucial for material
science. Here, the mechanisms of different piezoresponsive luminescence
of 2,3,4,5-tetraphenylthiophene (TPT) and 2,3,4,5-tetraphenylfuran
(TPF) crystals are explored. The experimental results combined with
density functional theory (DFT) theory calculation indicate that the
PIEE phenomenon is possibly exhibited in V-shape arrangement for the
reason of the weak π–π interactions. This study
not only gains deep insight into the relationship between optical
properties and structural evolution but also puts forward a strategy
for designing PIEE materials from the point of molecular arrangement.
Triboelectric nanogenerators with the function of harvesting human motion energy have attracted wide attention. Here, we demonstrate a shared-electrode and nested-tube structure triboelectric nanogenerator (SNTN) for harvesting human motion energy. The design of the SNTN employs flexible silicone rubber as the negative friction material and Ni-coated polyester conductive textile as the positive friction material and the electrode material. The entire structure consists of an inner triboelectric unit and an outer triboelectric unit. The inner triboelectric unit is formed by a hollow inner tube and a hollow middle tube, while the hollow middle tube and a hollow outer tube constitute the outer triboelectric unit. The hollow middle tube is used as the shared tube, and the electrode in the middle tube is used as the shared electrode of the two triboelectric units. Our research demonstrates that the output performance of the SNTN was improved significantly compared with a single triboelectric unit due to the cooperation of the two triboelectric units. When the SNTN is pressed by 300 N external force, output open-circuit voltage of 180 V and output short-circuit current of 8.5 μA can be obtained. The output electrical energy can light up 31 light-emitting diodes (LEDs) connected serially (displaying “XZTC”) and can drive a digital clock after rectifying storage, which shows application prospects in the field of illuminating devices and portable electronics.
Mechanoresponsive luminescent (MRL) materials have drawn extensive concern due to their potential applications in mechanical sensors, memory chips, and security inks; especially these possessing high emission efficiency. In this work, we found trans-stilbene crystal exhibited two different pressure-induced emission enhancement (PIEE) behaviors at different pressure areas. The structural characterizations combined with density functional theory calculation indicate that the first emission enhancement was due to the decrease of nonradiation transition by the weaken of energy exchange process between atoms and lattice. And the second emission enhancement was attributed to the strengthen of C–H…C interactions from the non-planarization comformation. The results regarding the mechanoresponsive behavior of trans-stilbene offered a deep insight into PIEE from the structural point of view, which will facilitate the design of and search for high-performance MRL materials.
Most researchers use features of diastolic murmurs to identify coronary artery disease. However, the diastolic murmurs of coronary artery disease are usually very weak and are easily contaminated by noise and valvular murmurs. Therefore, the diagnostic accuracy of coronary artery disease when only using diastolic murmurs is not well. An algorithm for improving the accuracy in the identification of coronary artery disease by combining the features of the first heart sound and diastolic murmurs was proposed. Firstly, a first heart sound feature extraction algorithm was used to identify coronary artery disease from noncoronary artery disease. Secondly, the Empirical Wavelet Transform algorithm was used to decompose the diastolic heart sound into three modes, and the spectral energy of each mode was calculated to distinguish coronary artery disease from noncoronary artery disease. Then, the features of the fist heart sound, the second diastolic spectral energy, and the parameter P3, which was used to discriminate the diastolic murmurs in coronary artery disease and in valvular disease, were combined together to improve the diagnostic accuracy of coronary artery disease. The comparison experiment results show that the accuracy of the proposed algorithm is superior to some state-of-the-art methods when they are used to diagnose coronary artery disease.
Multiparticle azimuthal correlations in central nucleus-nucleus collisions at high energy are described by a simple formula. The calculated results are in agreement with the experimental data of carbon and oxygen induced interactions at Dubna energy. The comparison between the calculated results and experimental data shows that particles are emitted isotropically in the rest frame of the emission sources, and the emission sources have movements in momentum space.
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