Pre-oxidation was introduced to improve the resistance of electroplated pure, 5 mm CeO 2 -dispersed, and 9-15 nm CeO 2 -dispersed Ni 3 Al coatings to coke formation and metal dusting in 24.4%CO-73.3%H 2 -2.3%H 2 O at 650 8C. Coke formation and metal dusting of pre-oxidized Ni 3 Al-based coatings were retarded up to 200 h owing to a thin Al 2 O 3 scale induced during preoxidation. The long-term effectiveness of pre-oxidation nonetheless depended on the integrity of Al 2 O 3 scale. The pure Ni 3 Al coating suffered severe spallation after pre-oxidation and thereby showed the worst long-term resistance. Two pre-treated 9-15 nm CeO 2 -dispersed Ni 3 Al coatings exhibited the best long-term resistance to carbon attack because nano-CeO 2 particles maintained a full coverage of Al 2 O 3 scale on the coatings. Two 5 mm CeO 2 -dispersed Ni 3 Al coatings showed significant spallation after pre-oxidation because of an overdoping effect and experienced coke formation and metal dusting during long-term exposure.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.