Data are compiled and evaluated for collision processes of excitation, dissociation, ionization, attachment, and recombination of hydrogen molecules and molecular ions (H 2+ , H 3+) by electron impact as well as for properties of their collision products.
New experimental data on double-ionization cross sections of neutral atoms, positive and negative ions by electron impact are reported. These and other relevant data are compared with recent multiple-ionization semiempirical formulae extended for the case of two-electron ionization. Theory gives analytical dependence of the double-ionization cross sections on the main parameters of the collision system in a wide energy range. For the He atom, He-like ions and H − ion high-energy asymptotic behaviour of the double-ionization cross sections are considered on the basis of a quantum mechanical treatment. Suggested cross section scaling for fast collisions, employing a target-effective nuclear charge, is in good agreement with experimental data.
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