Nano gamma-alumina support was prepared successfully by Sol-gel method using aluminum nitrate without and with carbon nanotubes as a template at different calcination temperatures (600, 650, and 700°C) and then loaded with 0.3% of platinum and 0.3% of tungsten by the wet- impregnation method. X-ray diffraction (XRD), thermal gravimetric analysis (TGA), atomic force microscope (AFM), field emission scanning electron microscopy (FE-SEM) and (BET) surface area were used to characterize the prepared nano catalyst. The best results obtained were 389.34 m2/gm surface area, 0.468 cm3 /gm pore volume, 8.07 nm pore size and 42.71 nm average particle size for the prepared nana gamma-alumina at a calcination temperature of 600°C.