Key indicators: single-crystal X-ray study; T = 293 K; mean (C-C) = 0.003 Å; R factor = 0.037; wR factor = 0.112; data-to-parameter ratio = 12.9.The structure of the title organic-inorganic hybrid material, C 8 H 12 N + ÁNO 3 À , results mainly from electrostatic interactions and bifurcated N-HÁ Á ÁO and C-HÁ Á ÁO hydrogen bonds. Organic 2,6-xylidinium cations and inorganic nitrate anions interact to form a three-dimensional hydrogen-bond network.
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