No abstract

Thermal management is crucial to guarantee the normal operation of light-emitting diodes (LEDs) Phase change heat sink is superior to traditional metal solid heat sink due to very small thermal resistance. In this study, a new type of phase change heat sink for high power LEDs is first designed. Then, the fabrication process of boiling structures at the evaporation surface of the phase change heat sink is discussed and analyzed. To make a comparison and deep discussion, the machining process is simulated through the FEM (finite element analysis) software, DEFORM-3D. Last but not least, heat transfer performance of the fabricated phase change heat sink is tested. Results have shown that the designed new type of phase change heat sink has superior heat transfer performance and is suitable for heat dissipation of high-power LEDs.

The objective of this study was to fabricate anti-gravity heat pipes with a tapering column phase-change chamber and changeable cross-sectional wick structure. The thermal performances of the anti-gravity heat pipes were experimentally investigated. Results show that the thermal resistances of the different heat pipes are less than 0.03 °C/W, except for the sharp conical chamber heat pipe under anti-gravity heating conditions (0.121 °C/W). Start-up times of different types of heat pipes are similar and the temperatures are steady within 3 to 5 min. The heat transfer ability of a conical chamber is always better than that of a cylindrical one. The performance of the sharp conical chamber heat pipe is the best under gravity assistance heating conditions. Contrarily, the blunt conical chamber heat pipe has the best heat transfer ability under anti-gravity heating conditions. Moreover, the heat transfer capability of the blunt conical chamber heat pipe is unaffected by the relative position of the heat and cold sources, which is suitable for constant temperature cooling applications with frequent switching of the heat and cold sources.

Copolymerization of propargylether having antipyrine group (PT) and N‐(tert‐butoxycarbonyl)‐l‐valine‐N‐propargylamide (LA) was conducted with (nbd)Rh+[η6‐C6H5B−(C6H5)3] as a catalyst to obtain novel antipyrine‐functionalized chiral copolymer. The controllable secondary structure of the copolymers by different unit ratio or solvent environment led to a controlled fluorescence of the side‐chain antipyrine. Poly(LA88‐co‐PT12) exhibited a large specific rotation and a circular dichroism (CD) signal, while it emitted very stronger fluorescence. From CD and ultraviolet–visible spectra, the regular structure of poly(LA88‐co‐PT12) was destroyed, and the random coil was formed with temperature increase. The helical conformation of poly(LA75‐co‐PT25) disappeared by the addition of MeOH to CHCl3 solution, while the fluorescence signal also became weaker than in CHCl3 solution. It is suggested that the copolymer conformation much influenced the performance of chromophores. In the present study, the helix conformation could induce fluorescence enhancement. Copyright © 2015 John Wiley & Sons, Ltd.