Storage (G′) and loss (G″) shear moduli of supercooled glucose have been measured at thirteen temperatures from 27.4 to 41.1°C in the frequency range from 0.3 to 1.8 cps. Shear creep has been measured at four temperatures from 41.1 to 47.6°C. The temperature dependence of the storage moduli and the creep compliance was described by reducing the time and frequency scales with shift factors calculated from the WLF equation, the constants corresponding to a fractional free volume of 0.026 at 41.1°C and a free volume expansion coefficient of 3.6×10−4 deg−1. The loss moduli plotted against reduced frequency did not give a single composite curve, however. Conversion of the dynamic measurements to creep compliance by approximation methods provided the latter function over ten decades of logarithmic time except for a gap of three decades in the middle of the range. At long times, the creep was indistinguishable from viscous flow; the viscosity at 41.1°C was 1.82×1010 poise. At short times, the limiting creep compliance appeared to be 0.32×10−16 cm2/dyne, and there was an additional time-dependent compliance of at least this magnitude with a broad distribution of retardation times. The relaxation and retardation spectra were calculated for this region.

Ce document a été généré automatiquement le 30 avril 2019. © Cahiers de recherches médiévales et humanistes Éditer l'encyclopédie de Barthélemy l'Anglais Cahiers de recherches médiévales et humanistes, 6 | 1999 Le De proprietatibus rerum a été un succès de librairie. Voici une quinzaine d'années, on en connaissait une petite centaine de manuscrits latins. En 1992, le volume de commentaires Éditer l'encyclopédie de Barthélemy l'Anglais Cahiers de recherches médiévales et humanistes, 6 | 1999

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