We have studied lattice dynamic properties of SrTiO 3 thin films from 5 to 300 K using metaloxide bilayer Raman scattering. First-order zone-center optical phonons, symmetry forbidden in single crystals, have been observed in the thin films, indicating strain-induced lowering of symmetry. The asymmetric line shape of the TO 2 phonon is interpreted as evidence for micropolar regions in the thin films, likely due to oxygen vacancies. The optical phonon lines and the asymmetry persist up to room temperature. [S0031-9007(99)09277-7]
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