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An organic-inorganic hybrid silver iodobismuthate characteristic of the infrequent [Ag2BiI6L2] cluster (L = I or I3) and the unique Ag/Bi molar ratio (2/1), namely, [Zn(bipy)3]2Ag2BiI6(I)1.355(I3)1.645 (bipy = 2,2'-bipyridine; 1), has...

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Pursuits of new types of Pb-free heterometallic halides adequate for the photovoltaic applications are still urgent but challenging. Herein, by using the in situ-produced [(Me)2-(DABCO)]2+ (DABCO = 1,4-diazabicyclo[2.2.2]octane; Me =...