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Nanoparticles (NPs) from lanthanum oxide (La 2 O 3 ) and copper oxide (CuO) with spherical morphology were synthesized through precursor calcinations of copper and lanthanum carbonate and then using a bioactive shell membrane of eggshell. X-ray diffraction (XRD) analysis and scanning electron microscopy (SEM) were used to evaluate particle size, chemical structure, purity and morphology of the synthesized La 2 O 3 and CuO NPs. The XRD outcomes established the creation of the targeted compounds, SEM images obviously displayed morphology of the synthesized La 2 O 3 and CuO as spherical NPs with average particle sizes of roughly 35 and 30 nm, correspondingly. The catalytic ef-fects of these NPs on the thermal decomposition behavior of ammonium perchlorate (AP) were tested using differential scanning calorimetry (DSC) in coupling with thermogravimetric analysis (TG). The results of these experiments showed that the addition of 5 % La 2 O 3 nanoparticles has an attractive catalytic effect on the thermal decomposition of the AP. Moreover, AP thermal decomposition was facilitated by the addition of 5 % CuO NPs. A more accurate comparison was made between the catalytic effects of synthesized NPs via computing their thermal decomposition activation energies (E), DS # , DH # and DG # using diverse non-isothermal approaches.Keywords: Lanthanum oxide · Copper oxide · Ammonium perchlorate (AP) · Nanocatalyst effect · Thermal decomposition kinetic · Thermodynamic parameters[a] H. M. Pandas, M. Fazli

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Nanoparticles (NPs) of lead tetroxide (Pb3O4) with the spherical morphology were manufactured by the reaction of lead nitrate with sodium hydroxide, while the nanoparticles (NPs) of red iron oxide (Fe2O3) with similar morphology were fabricated by hydrothermal route in the presence of ferric chloride hexahydrate as the precursor. Evaluation of the chemical structure, the purity and the morphology of the manufactured Fe2O3 and Pb3O4 NPs was carried out by analysis via X-ray diffraction (XRD) as well as scanning electron microscope (SEM). The outcomes of XRD recognized establishment of the desired oxides, wherever the SEM images clearly exhibited the morphology of the manufactured Pb3O4 and Fe2O3 as the spherical NPs with an average particle sizes of near to 40 and 46 nm, respectively. The catalytic effect of the metallic oxide NPs on the perfection of ammonium perchlorate (AP) thermal decomposing was established by testing their AP nano-composites via differential scanning calorimetric (DSC) together with thermogravimetric analysis (TG). Thermal behavior studies displayed that adding of 5% Fe2O3/Pb3O4 NPs (as the mixture) delivers a concerned catalytic effect during AP thermal decomposition. Additionally, thermal decomposition of AP could be amended by adding of 2% Pb3O4 NPs. Further comparison of the NPs catalytic effects was obtained by computing the values of activation energies (E) and thermodynamic parameters (i.e., ΔS#, ΔH# and ΔG#) for their thermal decomposition by non-isothermal approaches.