A novel Ni-catalysed deamidative fluorination of twist amides with electrophilic fluorinating reagents is reported, affording diverse acyl fluorides in good yields.

We report herein the palladium-catalysed mono-selective C–H arylation of [2.2]paracyclophane (PCP) with diverse aryl iodides in the absence of any pendant directing groups, providing a straightforward and modular access to...

We report herein a cationic iridium-catalysed thioether-directed alkyne-azide cycloaddition reaction. Diverse 2-alkynyl phenyl sulfides can undergo cycloaddition with different azides in a regioselective fashion. The reaction features high efficiency, short...