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A hexakis(pyrenyloxy)cyclotriphosphazene is synthesized by the reaction of N3P3Cl6 with 2-hydroxypyrene, and its excimer emission through intramolecular interactions in solution and in the solid state has been investigated by fluorescence spectroscopy and X-ray crystallography. Thermal and electrochemical properties were investigated. A DFT benchmark study has been performed to evaluate the intramolecular interactions and molecular orbital levels by comparing with the experimental results.

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Synthesis and spectral properties of fluorene substituted cyclic and polymeric phosphazenes

Alidağı

Hacıvelioğlu

Tümay

et al. 2017

Inorganica Chimica Acta

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A new cyclotriphosphazene appended phenanthroline derivative as a highly selective and sensitive OFF–ON fluorescent chemosensor for Al 3+ ions

et al. 2016

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