A dye-sensitized solar cell (DSSC) was fabricated with a nanocrystalline TiO 2 film electrode on FTO glass, N719 dye, electrolytes (or CsSnI 3 ), and counter Pt electrode by incorporating it with single-walled carbon nanotubes (SWNTs). SWNTs were combined with TiO 2 film, CsSnI 3 , Pt electrode, separately, and the SWNTcontaining cell was compared with a pristine cell in cell performance. We also examined the performance change by pressing TiO 2 film, during cell fabrication, inside a high pressure chamber. Mostly, the change of conversion efficiency was compared for each cell, and an atomic force microscopy data were suggested to explain our results.
Cadmium sulfide (CdS) and cadmium selenide (CdSe) are sequentially assembled onto a nanocrystalline TiO2 film to create a quantum-dot (QD)-sensitized solar cell application by a successive ionic layer adsorption and reaction (SILAR) method. The results show that CdS and CdSe QDs have a complementary effect in the performance of light harvest of solar cell. Single-walled carbon nanotubes (SWNTs) are incorporated with a CdS/CdSe QDs solar cell by mixing them with TiC2 film to enhance electron transfer. SWNTs are also sprayed onto CdSe QDs (SWNTs onto CdSe) to apply p+ type properties of SWNTs. Absorbance is increased in a wide wavelength range. In particular, cells having the sprayed SWNTs onto the QDs show a clear increase in absorbance at a low wavelength region. The fill factor of CdS/CdSe QDs solar cell with SWNTs is higher than that without SWNTs, indicating the decrease in loss of electron from TiO2 to QDs. Short-circuit current in a QD-sensitized solar cell having SWNTs on CdSe shows maximum value. Photo-current conversion efficiency of cells is increased in both cell types containing SWNTs at 10~17% compared with pristine cells. We expect that solar cells using SWNTs will affect future energy technology and devices.
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